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A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior
Journal article   Peer reviewed

A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior

Humphrey L. C. Feltham, Rodolphe Clérac, Annie K. Powell and Sally Brooker
Inorganic chemistry, Vol.50(10), pp.4232-4234
16/05/2011
Handle:
https://hdl.handle.net/10523/34072

Abstract

Chemical Sciences Inorganic chemistry Material chemistry
[CuII3TbIII(LPr)(NO3)2(MeOH)(H2O)2]-(NO3) 3 3H2O is a rare example of a 3d-4f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.

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