A dynamic covalent approach to [PtnL2n]2n+ cages

Quinn V. C. van Hilst; Aston C. Pearcy; Dan Preston; L. James Wright; Christian G. Hartinger; Heather J. L. Brooks; James D. Crowley

doi:10.1039/d4cc00323c

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A dynamic covalent approach to [PtnL2n]2n+ cages

Journal article

Peer reviewed

A dynamic covalent approach to [PtnL2n]2n+ cages

Quinn V. C. van Hilst, Aston C. Pearcy, Dan Preston, L. James Wright, Christian G. Hartinger, Heather J. L. Brooks and James D. Crowley

Chemical communications, Vol.60(32), pp.4302-4305

16/04/2024

DOI: https://doi.org/10.1039/d4cc00323c

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https://hdl.handle.net/10523/24347

Abstract

Chemistry

X-ray crystallography

platinum(II) architecture

molecular structures

A dynamic covalent approach was exploited to generate a family of homometallic [PtₙL₂ₙ](²ⁿ⁺) cage (predominantly [PtₙL₄](⁴⁺) systems) architectures. The family of platinum(ii) architectures were characterized using H-1 nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.

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Record Identifier: 9926514749501891
Title: A dynamic covalent approach to [PtnL2n]2n+ cages
Creators: Quinn V. C. van Hilst
Aston C. Pearcy
Dan Preston
L. James Wright
Christian G. Hartinger
Heather J. L. Brooks
James D. Crowley
Publication Details: Chemical communications, Vol.60(32), pp.4302-4305
Academic Unit: Pathology and Molecular Medicine (DSM); Chemistry
Publisher: Royal Society of Chemistry
Grant note: UOA1726 / Marsden Fund; Royal Society of New Zealand; John Edmond Trust; Department of Chemistry, University of Otago; University of Otago; MacDiarmid Institute for Advanced Materials and Nanotechnology
Date published ; e-published: 16/04/2024
Comment: The published version is not available in full-text in OUR Archive. Where available, a link to the published version is provided (check the DOI and/or the Files and links section). The full-text item may be open access on the publisher's website. An earlier version of the work (such as authors' accepted manuscript following peer-review or unreviewed preprint/author's original version) may be available in the Files and links section of this record. Alternatively, readers may have subscription access to the full-text from the publisher.
Language: English
Resource Type ; Subtype: Journal article

A dynamic covalent approach to [PtnL2n]2n+ cages

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