Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

Nicholas G. White; Jonathan A. Kitchen; John A. Joule; Sally Brooker

doi:10.1039/c2cc32018e

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Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

Journal article

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Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

Nicholas G. White, Jonathan A. Kitchen, John A. Joule and Sally Brooker

Chemical communications (Cambridge, England), Vol.48(50), pp.6229-6231

25/06/2012

DOI: https://doi.org/10.1039/c2cc32018e

Abstract

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Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [Cu-8(II)(dpt)(4)(OH)(4)(OAc)(8)]; OAc = acetate anion, and dpt(-) = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [Cu-4(II)(dpt)(2)(OH)(OMe)(OAc)(4)].

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Record Identifier: 9926517972801891
Title: Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex
Creators: Nicholas G. White
Jonathan A. Kitchen
John A. Joule
Sally Brooker
Publication Details: Chemical communications (Cambridge, England), Vol.48(50), pp.6229-6231
Academic Unit: Chemistry
Publisher: Royal Soc Chemistry
Date published ; e-published: 25/06/2012
Language: English
Resource Type: Journal article

Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

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