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Hysteretic spin crossover in iron(II) complexes of a new pyridine-triazole-pyrazine ligand is tuned by choice of NCE co-ligand
Journal article   Peer reviewed

Hysteretic spin crossover in iron(II) complexes of a new pyridine-triazole-pyrazine ligand is tuned by choice of NCE co-ligand

Ross W. Hogue, Reece G. Miller, Nicholas G. White, Humphrey L. C. Feltham, Guy N. L. Jameson and Sally Brooker
Chemical communications (Cambridge, England), Vol.50(12), pp.1435-1437
01/01/2014
DOI: https://doi.org/10.1039/c3cc43922d

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A family of three new mononuclear complexes of the general form [Fe(L-pz)(2)(NCE)(2)] has been prepared (L-pz = 4-p-tolyl- 3-(2-pyrazinyl)5-(2-pyridyl)- 1,2,4- triazole; E = S, Se, BH3). All three exhibit spin crossover, in two cases with hysteresis, with T-1/2 being predictably tuned by varying the coordinated anion.

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