Identification of the Water Amidogen Radical Complex

Courtney P. Ennis; Joseph R. Lane; Henrik G. Kjaergaard; Allan J. McKinley

doi:10.1021/ja808109m

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Identification of the Water Amidogen Radical Complex

Journal article

Peer reviewed

Identification of the Water Amidogen Radical Complex

Courtney P. Ennis, Joseph R. Lane, Henrik G. Kjaergaard and Allan J. McKinley

Journal of the American Chemical Society, Vol.131(4), pp.1358-1359

04/02/2009

DOI: https://doi.org/10.1021/ja808109m

Abstract

Chemistry

Chemistry, Multidisciplinary

Physical Sciences

Science & Technology

The water amidogen radical complex (H2O-NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O-NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

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Record Identifier: 9926529229701891
Title: Identification of the Water Amidogen Radical Complex
Creators: Courtney P. Ennis
Joseph R. Lane
Henrik G. Kjaergaard
Allan J. McKinley
Publication Details: Journal of the American Chemical Society, Vol.131(4), pp.1358-1359
Academic Unit: Chemistry
Publisher: Amer Chemical Soc
Grant note: Foundation for Research, Science, and Technology; New Zealand Foundation for Research, Science and Technology Australian Commonwealth Government; Australian Government Royal Society of New Zealand
Date published ; e-published: 04/02/2009
Language: English
Resource Type; Subtype: Journal article

Identification of the Water Amidogen Radical Complex

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