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Iron oxide mediated direct C-H arylation/alkylation at alpha-position of cyclic aliphatic ethers
Journal article   Peer reviewed

Iron oxide mediated direct C-H arylation/alkylation at alpha-position of cyclic aliphatic ethers

Parvinder Pal Singh, Satish Gudup, Srinivas Ambala, Umed Singh, Sumit Dadhwal, Baldev Singh, Sanghapal D. Sawant and Ram A. Vishwakarma
Chemical communications (Cambridge, England), Vol.47(20), pp.5852-5854
28/05/2011
DOI: https://doi.org/10.1039/c1cc11094b
Handle:
https://hdl.handle.net/10523/34142

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
We report a new and efficient iron oxide catalyzed cross-coupling reaction between organometallic species such as alkyl/arylmagnesium halides or organolithium species and alpha-hydrogen bearing cyclic aliphatic ethers via activation of C(sp(3))-H. This is the first example of iron oxide mediated direct C-C bond formation without expensive or toxic ligands.

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