Abstract
•Vulnerability of Māori textiles to photodegradation depends on dye type.•Colourfastness to light of dyed muka is greater than previously thought.•Muka tensile properties unaffected by accelerated light-ageing up to 10 Mlux hours.•Molecular change in response to light-ageing observed only for tanekaha-dyed muka.
Māori are the indigenous people of Aotearoa New Zealand. Textiles produced by Māori have high cultural importance and aesthetic appeal and are consequently often on display, despite being thought to be vulnerable to photodegradation, with loss of colour and fibre embrittlement reported for artefacts held in collections worldwide. Consequently, these textiles are managed as ‘sensitive category’ artefacts when exhibited, despite a lack of information regarding their specific response to light. This project used multiple techniques to assess the influence of light exposure on colour, tensile properties and molecular structure of dyed muka [fibre commonly found in Māori textile artefacts; non-dyed, tanekaha (red/tan dye), paru (black dye)]. A combination of accelerated light-ageing (conventional mercury vapour and microfading), tensile testing, attenuated total reflectance infrared (ATR-IR) and Raman spectroscopy techniques were applied. Tanekaha-dyed muka was the least light fast in comparison to other dye types (tanekaha/non-dyed/paru: fading rate equivalent to ISO Blue Wool standard 1-2/3-4/3-4, one just noticeable fade at 0.4/3.6/10 Mlux hours, respectively). Light exposure (10 Mlux hours) decreased the tensile properties (tenacity, extensibility and toughness) of paru-dyed muka only, with this dye type also demonstrating lesser tensile properties compared to other dye types prior to light exposure. ATR-IR spectra combined with partial lest squares regression (PLSR) indicated tanekaha-dyed muka had some detectable chemical changes correlated with light aging (PLSR model slope=0.69, RMSE=1.7 and R2=0.68). No correlation was found for non- and paru-dyed muka spectra (PLSR model slopes≤0.45, RMSE>2.5 and R2≤0.4). Although Māori textiles containing dyed muka are generally assigned to a sensitive category for museum display, the results from this study suggest that these textiles are more stable to light than previously thought, particularly non- and paru-dyed muka. Despite fears held by museum practitioners that colour change while on exhibition is also indicative of other degradation, results did not support this contention. Furthermore, the study enabled comparison of results gained by two methods of artificial ageing (conventional light-ageing and microfading) increasing researcher confidence about making recommendations to museums and furthering knowledge about new techniques of establishing light stability when on display.