Abstract
A new family of mononuclear [Fe
(Rdpt)
(NCE)
] complexes (E = S, Se, or BH
) is formed by 1:2 reaction of [Fe
(pyridine)
(NCE)
] with the monotopic pyridyl triazole ligand 4-(4-methylphenyl)-3-(2-pyridinyl)-5-phenyl-4H-1,2,4-triazole (tolpyph). The three complexes are obtained as six different solvatomorphs: [Fe
(tolpyph)
(NCS)
]·H
O (1·H
O), 1·1.5CH
OH·0.5H
O, [Fe
(tolpyph)
(NCSe)
] (2), 2·1.5H
O, [Fe
(tolpyph)
(NCBH
)
] (3), and 3·H
O. Single-crystal X-ray diffraction reveals that 1·1.5CH
OH·0.5H
O and 2 are high-spin (HS) at 100 K, while 3 is low-spin (LS) at 100 K and HS at 373 K. Compound 3 is the first structurally characterized example of an [Fe
(Rdpt)
(NCE)
]-type complex with NCBH
co-ligand: the crystal packing is dominated by aromatic stacking interactions. Solid-state magnetic measurements show that 1·H
O and 2·1.5H
O remain HS down to 50 K, whereas 3·H
O undergoes spin crossover (SCO) with a T
of 309 K, slightly above room temperature. A literature survey of analogous trans-[Fe
(Rdpt)
(NCX)
]-type complexes (53 distinct crystal structures) shows that for the complexes that are SCO active in the solid state the Fe-N≡C(X) angle is usually close to straight, 162-178°, whereas it is usually lower, 142-159°, for the complexes that remain HS. UV-vis studies in CHCl
solution show that in each case the use of a 6:1 ratio of tolpyph/Fe(II) is required to ensure the iron(II) is present in solution as [Fe
(tolpyph)
(NCE)
]. Interestingly, using this ratio, all three compounds are SCO-active in CDCl
solution-in dramatic contrast to the solid-state findings. Specifically, while compounds 1 and 2 are not SCO-active in the solid state (they remain HS), they undergo gradual SCO in CDCl
solution, with T
values of 290 and 310 K, respectively. In CDCl
solution, compound 3 has a T
value of 288 K, which is 21 K lower than in the solid state. These results highlight the differences between solid state (ligand field; crystal packing) and solution (ligand field; solvation) effects on SCO, with the latter studies revealing room-temperature SCO for all three of these complexes.