Spin crossover in co-crystallised 2: 1 cis : trans [Fe-II(pldpt)(2)(NCS)(2)] occurs only in 1/3 of the iron centres

Jonathan A. Kitchen; Guy N. L. Jameson; Jeffery L. Tallon; Sally Brooker

doi:10.1039/b927036a

Back

Spin crossover in co-crystallised 2: 1 cis : trans [Fe-II(pldpt)(2)(NCS)(2)] occurs only in 1/3 of the iron centres

Journal article

Peer reviewed

Spin crossover in co-crystallised 2: 1 cis : trans [Fe-II(pldpt)(2)(NCS)(2)] occurs only in 1/3 of the iron centres

Jonathan A. Kitchen, Guy N. L. Jameson, Jeffery L. Tallon and Sally Brooker

Chemical communications (Cambridge, England), Vol.46(18), pp.3200-3202

01/01/2010

DOI: https://doi.org/10.1039/b927036a

Abstract

Chemistry

Chemistry, Multidisciplinary

Physical Sciences

Science & Technology

The first spin crossover (SCO) active sample of co-crystallised stereoisomers (cis : trans, 2 : 1) is fully high spin (HS) at room temperature but displays temperature mediated SCO in which only a third of the iron(II) centres change spin state.

Metrics

1 Record Views

Details

Record Identifier: 9926517084801891
Title: Spin crossover in co-crystallised 2: 1 cis : trans [Fe-II(pldpt)(2)(NCS)(2)] occurs only in 1/3 of the iron centres
Creators: Jonathan A. Kitchen
Guy N. L. Jameson
Jeffery L. Tallon
Sally Brooker
Publication Details: Chemical communications (Cambridge, England), Vol.46(18), pp.3200-3202
Academic Unit: Chemistry
Publisher: Royal Soc Chemistry
Grant note: Marsden Fund; Royal Society of New Zealand; Marsden Fund (NZ) Tertiary Education Commission (NZ) MacDiarmid Institute for Advanced Materials and Nanotechnology University of Otago
Date published ; e-published: 01/01/2010
Language: English
Resource Type: Journal article

Spin crossover in co-crystallised 2: 1 cis : trans [Fe-II(pldpt)(2)(NCS)(2)] occurs only in 1/3 of the iron centres

Abstract

Related links

Metrics

Details

Usage Policy