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The Synthesis of (+/-)-Oxyisocyclointegrin
Journal article   Peer reviewed

The Synthesis of (+/-)-Oxyisocyclointegrin

Robert J. Smith, Rebekah L. Bower, Scott A. Ferguson, Rhonda J. Rosengren, Greg M. Cook and Bill C. Hawkins
European journal of organic chemistry, Vol.2019(7), pp.1571-1573
21/02/2019
DOI: https://doi.org/10.1002/ejoc.201801751
Handle:
https://hdl.handle.net/10523/28284

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
The total synthesis of oxyisocyclointegrin is described. The key steps in the synthesis included a Tsuji-Trost allyl migration to exclusively afford the corresponding monoallylated 1,3-diketone and a photochemical initiated oxidative cyclization to forge the oxepine core.

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