Abstract
The complex collisional properties of atoms fundamentally limit investigations into a range of processes in many-atom ensembles. In contrast, the bottom-up assembly of few- and manybody systems from individual atoms offers a controlled approach to isolating and studying such collisional processes. Here, we use optical tweezers to individually assemble pairs of trapped Rb-85 atoms, and study the spin dynamics of the two-body system in a thermal state. The spin-2 atoms show strong pair correlation between magnetic sublevels on timescales exceeding one second, with measured relative number fluctuations 11.9 +/- 0.3 dB below quantum shot noise, limited only by detection efficiency. Spin populations display relaxation dynamics consistent with simulations and theoretical predictions for Rb-85 spin interactions, and contrary to the coherent spin waves witnessed in finite-temperature many-body experiments and zero-temperature two-body experiments. Our experimental approach offers a versatile platform for studying two-body quantum dynamics and may provide a route to thermally robust entanglement generation.